This hack should serve your purpose. It checks the inbox for an email address that matches the email address being submitted. If it is a match, no data is recorded in the database and the user is redirected to another page. You could put a message on the redirect page informing the user that they are already registered.
Open sc_admin/include/contact.php
Add the following code after line 145:
$email = $posted["email"];
$query = "SELECT id FROM $table_form_post WHERE email='$email' LIMIT 1";
$msg_result = mysql_query($query) or die(sql_err_handler($query, mysql_error()));
if (mysql_numrows($msg_result) == 0) {
Add the following code after line 301:
} else {
header("Location: contact_failed.html");
exit;
}